| Date | Home | Away | Result |
|---|---|---|---|
| 12/09/25 20:00 | FC Sevilla | FC Elche | 2-2 |
| 13/09/25 13:00 | FC Getafe | Real Oviedo | 2-0 |
| 13/09/25 15:15 | Real Sociedad | Real Madrid | 1-2 |
| 13/09/25 17:30 | Athletic Bilbao | Deportivo Alaves | 0-1 |
| 13/09/25 20:00 | Atletico Madrid | FC Villarreal | 2-0 |
| 14/09/25 13:00 | Celta Vigo | FC Girona | --- |
| 14/09/25 15:15 | UD Levante | Real Betis Sevilla | --- |
| 14/09/25 17:30 | CA Osasuna | Rayo Vallecano | --- |
| 14/09/25 20:00 | FC Barcelona | FC Valencia | --- |
| 15/09/25 20:00 | Espanyol Barcelona | RCD Mallorca | --- |